Sub-Doppler Spectroscopy of Benzene in the "Channel-three" Region

In addition to an increased accuracy in the determination of
structural parameters sub- Doppler spectroscopy of large molecules
is shown to render valuable information about intramolecular
processes and relaxation mechanisms. As an example we have measured
the Doppler-free rotationally resolved two-photon spectrum of two
vibronic bands of CsHs, 1461; and 14i1;. Compared with the 14i1:
band (EcxE :,:=css 2492 cm-') a drastically reduced number of sharp
lines is observed in the 14i1; band (Eence=ss 3 412 cm-I). The X =
0 rotational lines are still seen, while K # 0 lines disappear.
This can be understood in terms of Coriolis coupling between the
14'1' state and other vibrational states within S1 and a subsequent
om-radiative process. This coupling might be the explanation for
the drastic onset of line broadening in C6H6 at an excess energy of
3000 cm-', " channel three." The line broadening is then due to a
different process from that responsible for the population lifetime
of s1.